Methyltertbutyl ether, also known as tertbutyl methyl ether, methyl tbutyl ether or mtbe, is classified as a member of the dialkyl ethers. Ethers, such as methyl tertbutyl ether, can act as bases. And easy mtbe msds pdf to use mysql uses standard sql mysql compiles on a number of. The biotransformation of methyl tertbutyl ether, ethyl tertbutyl ether etbe, and tertamyl methyl ether tame was studied in humans and in rats after inhalation of 4 and 40 ppm of mtbe, etbe, and tame, respectively, for 4 hours, and the biotransformation of mtbe and tame was studied after ingestion exposure in humans to 5 and 15 mg in water. The tba conversion decreases with increasing calcination temperature and alkali metal ion exchange of h. Mtbemethyl tertiarybutyl ether is a chemical compound that is manufactured by the chemical reaction of methanol and isobutylene. Ethers may react violently with strong oxidizing agents. Public health goal for methyl tertiary butyl ether mtbe in drinking water. Mtbe is a gasoline additive used to increase octane number that is produced from methanol and isobutylene. Mtbe methyltertbutyl ether should be considered a potential human carcinogen due to an increase in leydig interstitial cell tumors of testes in male rats and an increase in. Mysql free tutorial pdf download mysql free tutorial pdf download mysql free tutorial pdf download download.
Methyl tertbutyl ether recommended use laboratory chemicals. This page was last edited on 12 august 2019, at 19. Respiratory irritation, dizziness, and disorientation have been reported by some motorists and occupationally exposed workers. Keep away from heat, hot surfaces, sparks, open flames and other. Do not allow contact with soil, surface or ground water. High purity mtbe is used as a solvent in the pharmaceutical industry and as a lab solvent.
Other pertinent literature is also presented, but is described in less detail than the key studies. Biodegradation of methyl tertbutyl ether mtbe and its. Exposure may occur by breathing air contaminated with auto exhaust or gasoline fumes while refueling autos. Mtbe resource guide european fuel oxygenates association. Hydrolysis of tertbutyl methyl ether mtbe in dilute. This page contains pharmcos material safety data sheets. Mtbe is produced in very large quantities over 200,000 barrels per day in the u. Methyl tertbutyl ether 1634044 hazard summary methyl tertbutyl ether is used as a gasoline additive. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa. They form salts with strong acids and addition complexes with lewis acids.
It has a distinctive odor that most people find disagreeable. Mtbe is widely used in global markets as a gasoline oxygenate. Increasing the reaction temperature results in an increase of tba conversion with concomittant decrease of mtbe selectivity. Methyl tertbutyl ether mtbe is a flammable liquid with a distinctive, disagreeable odor. Fate of mtbe relative to benzene in a gasoline contaminated aquifer 199398 by james e. Download free course a multiple jpeg files to pdf converter online mysql. Our msds database is an easy to use, do it yourself tool, and best of all. When clicked the sheets are downloaded to your harddrive in a. Physical and thermodynamic properties of pure chemicals data compilation. Mtbe is manufactured via the chemical reaction of methanol and isobutylene.
All structured data from the file and property namespaces is available under the creative commons cc0 license. Mtbe appears to be degraded readily in the presence of oxygen but is recalcitrant under the anaerobic conditions prevalent in the subsurface, and can be converted into the more toxic compound tertbutanol tba. Mtbe is a volatile, flammable, and colorless liquid that is sparingly soluble in water. Box 2650 tulsa, oklahoma 74101 for emergency source information contact. Pdf occurrence of mtbe in heating oil and diesel fuel in.
Safety data sheet sds petrochemical corporation of. Both cultures were capable of cometabolizing mtbe and the metabolites, tertbutyl formate tbf and tertbutyl alcohol tba. It has weak aesthetic properties, and prolonged exposure to high concentrations may cause signs or symptoms of cns depression. Files are available under licenses specified on their description page. Methyl tbutyl ether mtbe methyl tbutyl ether mtbe is a clear, colorless organic liquid compound. Eximpulse services will provide you the latest and relevant market intelligence reports of mtbe import data you can use this mtbe import data for multiple kinds of analysis. If the file has been modified from its original state, some details such as the timestamp may not fully reflect those of the original file. The complex between diethyl ether and boron trifluoride is an example. In other reactions, which typically involve the breaking of the carbonoxygen bond. Methyl tertbutyl ether mtbe is a contaminant of concern to groundwater resources due to its persistence in subsurface environments. This file contains additional information such as exif metadata which may have been added by the digital camera, scanner, or software program used to create or digitize it. This lack of reactivity has led to concerns of the longterm impacts of mtbe in groundwater. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy.
Adobe acrobat pdf files are supplied to allow use of this product with a wide variety of software, hardware, and operating systems dos, windows, mac, and unix. Although hydrolysis in the presence of strong acids has been recognized as a mechanism for mtbe transformation, it has been discounted as a significant reaction under. The statewide sampling program confirmed the widespread occurrence of mtbe in heating oil and diesel fuel. Material safety data sheet gasoline, all grades msds no. Methyl tertbutyl ether mtbe, also known as tertbutyl methyl ether, is an organic compound. A complex blend of petroleumderived normal and branchedchain. Mtbe is the common name for a synthetic chemical called methyl tertbutyl ether. We ask that users who download significant portions of the database cite the hmdb. Dialkyl ethers are organic compounds containing the dialkyl ether functional group, with the formula ror, where r and r are alkyl groups. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials see section 10 and food and drink. Be sure to describe clearly what you are changing and how.
Click on any of the following chemicals below to download the msds sheet. Mtbe was detected in all samples collected during our sampling program at concentrations. The transport of mtbe was simulated using two numerical modeling approaches. Mtbe production material balance project you manage a chemical plant within a refinery complex that produces 60,000 tonney of methyl tertiarybutyl ether mtbe. This is classified as a dangerous good for transport and may be subject to additional shipping charges. Methanol is purchased but the isobutylene is obtained from a refinery stream. Mtbe is also used as a chemical intermediate to produce high purity isobutylene. It was first introduced as an additive for unleaded gasolines in the 1980s to enhance octane ratings. Methyl tertbutyl ether mtbe, also known as tertbutyl methyl ether, is an organic compound with a structural formula ch 3 3 coch 3. These files can be easily viewed in adobe acrobat reader. Impacts of ethanol on anaerobic production of tertbutyl. Mtbe methyltertbutyl ether should be considered a potential human carcinogen due to an increase in leydig interstitial cell tumors of testes in male rats and an increase in lymphomas, leukemias, and uterine sarcomas in female rats. The other automakers have been very quiet about biodiesel a stance due to change as new diesel vehicles come to the market in the next few years.
Articles of methyl tertbutyl ether are included as well. Contains benzene, which has been classified as a carcinogen by the national toxicology program ntp. Methyl tertbutyl ether safety data sheet according to federal register vol. The catalytic results are correlated with the surface. Mtbe methyl tertiarybutyl ether is a chemical compound that is manufactured by the chemical reaction of methanol and isobutylene. Search our product to see the coa msds for microbiology products, molecular biology products, animal cell culture, plant tissue culture, chemicals and lab equipments. Mtbe synthesis from tertbutyl alcohol tba and methanol has been studied using beta zeolites. Methyl tertbutyl ether mtbe is a mucosal and eye irritant. Download fulltext pdf production of 20,000 mtpd of methyl tertiarybutyl ether mtbe from methanol and butylene by catalytic conversion thesis pdf available october 2016 with 4,545 reads. Contains benzene, which can cause blood disease, including anemia. In the unlikely event of ingestion of mtbe, appropriate lavage procedures should be considered to avoid accidental aspiration of the product. Drift studies for the reaction and adsorption of alcohols and isobutylene on acidic resin catalysts and the mechanism of etbe and mtbe synthesis. It is a flammable liquid made from combinations of chemicals like isobutylene and methanol. Pdf production of 20,000 mtpd of methyl tertiarybutyl.